Immersion exposures of 304 stainless steel ground to a #4 finish were conducted in brines representative of the chemistry of sea salt aerosols at low (40%) and high (76%) relative humidity (RH). Low-RH-equivalent brines resulted in cross-hatched pits, whereas high-RH-equivalent brines produced ellipsoidal, faceted pits. Distinct surface micro-cracking was observed to be associated only with cross-hatched pits and appeared to correlate with a high concentration of dissolved carbonate species in low-RH-equivalent solutions, while being absent in the high-RH-equivalent brines. Correlating these results to brine composition suggested that the concentrations of MgCl<sub>2</sub> and dissolved carbonate species in the brines could, in the presence of machining-induced surface microstructure and residual stress, determine pit morphology in marine atmospheres, potentially impact stress corrosion cracking susceptibility and lifetime prediction. Keywords: Marine atmospheric corrosion ∙ Relative humidity ∙ Austenitic stainless steel ∙ Stress corrosion cracking

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2022
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